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Gas-side Problems. On coal-fired boilers, several kinds of deposit may be formed: slag type, alkali-matrix type (bonded), and the phosphate type, only obtained from coals with a high phosphate content (see Chapter 20). Alkali compounds and phosphates are volatilized and condensed on cooler metal surfaces; the alkalis react with sulphur dioxide and sulphur trioxide forming sulphates which bond to the metal …

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